This method outlines the analysis of volatile organic compounds in a variety of solid waste matrices including various air sampling trapping media, ground and surface water, soils, and sediments among others. The method requires not only demonstration of laboratory sample preparation and handling competence but instrument performance as well. The study presented here demonstrates the PerkinElmer® Clarus® SQ 8 GC/MS with purge and trap sample introduction both meets and exceeds the performance criteria set out in method 8260C and describes the analytical results and instrumental methodology.